Chlorido{4,4′,6,6′-tetra-tert-butyl-2,2′-[o-phenylenebis(nitrilomethylidyne)]diphenolato-κ4 O,N,N′,O′}manganese(III)
نویسندگان
چکیده
The asymmetric unit of the title Schiff base complex, [Mn(C(36)H(46)N(2)O(2))Cl], comprises two crystallographically independent mol-ecules. The Mn(III) centre in each mol-ecule adopts a distorted square-pyramidal geometry. Each Mn(III) ion is coordinated by the N(2)O(2) atoms of the tetra-dentate Schiff base ligand forming the basal plane and the coordinated chloride anion occupies the apical position. Four bifurcated intra-molecular C-H⋯O contacts stabilize the mol-ecular structure. In the crystal packing, mol-ecules are linked into dimers via inter-molecular C-H⋯Cl contacts and further stabilized by C-H⋯π inter-actions. The crystal studied was a non-merohedral twin, the refined ratio of the twin components being 0.441 (1):0.559 (1).
منابع مشابه
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